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mIRC - http://www.mirc.com/mIRC is a popular Internet Relay Chat client used by millions of people, and thousands of organizations, to communicate, share, play and work with each other on IRC networks around the world. Serving the Internet community for over a decade, mIRC has evolved into a powerful, reliable and fun piece of technology.
X-Chat - http://xchat.org/XChat is an IRC chat program for both Linux and Windows. It allows you to join multiple IRC channels (chat rooms) at the same time, talk publicly, private one-on-one conversations etc. Even file transfers are possible.
HydraIRC - http://www.hydrairc.com/HydraIRC is an open-source IRC client with an attractive and easy to use interface. It supports DCC Chat and File transfers, Connecting to multiple servers, Dockable Floating Tabbed Windows, Autohiding Windows, DLL Plugins, Channel Monitoring, Message Logs, Event Viewer, Themes, Color schemes, Buddy groups, Audible and Visual Notifications , Reg-Exp Highlighting, Favorites and much more.
KVIrc - http://www.kvirc.net/KVIrc is a free portable IRC client based on the excellent Qt GUI toolkit. KVirc is being written by Szymon Stefanek and the KVIrc Development Team with the contribution of many IRC addicted developers around the world.
REGISTERSyntax: /msg NickServ REGISTER password [email]
Syntax: REGISTER password [email]
Registers your nickname in the NickServ database. Once your nick is registered, you can use the SET and ACCESS commands to configure your nick's settings as you like them. Make sure you remember the password you use when registering - you'll need it to make changes to your nick later.
GROUPSyntax: /msg NickServ GROUP target password
Syntax: GROUP target password
This command makes your nickname join the target nickname's group. password is the password of the target nickname.
IDENTIFYSyntax: /msg NickServ IDENTIFY password
Syntax: IDENTIFY password
Tells NickServ that you are really the owner of this nick. Many commands require you to authenticate yourself with this command before you use them. The password should be the same one you sent with the REGISTER command.
LOGOUTSyntax: /msg NickServ LOGOUT
This reverses the effect of the IDENTIFY command, i.e. make you not recognized as the real owner of the nick anymore. Note, however, that you won't be asked to reidentify yourself.
DROPSyntax: /msg NickServ DROP [nickname]
Syntax: DROP [nickname]
Drops your nickname from the NickServ database. A nick that has been dropped is free for anyone to re-register.
RECOVERSyntax: /msg NickServ RECOVER nickname [password]
Syntax: RECOVER nickname [password]
Allows you to recover your nickname if someone else has taken it; this does the same thing that NickServ does automatically if someone tries to use a kill-protected nick.